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Chemistry Undergraduate

【急募】 大学の一般化学(量子力学)の問題です。 波動関数とか、ハミルトニアンとか、、、 わかる問題だけでもいいので解説をお願いします🙇‍♀️🙇‍♀️

全 xce 以下の問題に答えよ。 文字の定義は授業と同じ。 (1) 水素原子における電子のハミルトニアンは,次のように表される。 H² (2 0 - (1² or) + A = - 2me ər (3) • ● Cear HA EGERSAR 0. ●(r, 0,y) = Cerがシュレディンガー方程式の解になるようにαを定め, エネルギー固有値を求めよ。 答えはボーア半径 (do AREOR² = ト) を使った表記とすること。 meez (1,0p) = Crer coseがシュレディンガー方程式の解になるようにβを定め、エネルギー固有値を求め よ。 答えはボーア半径 (a 402. m₂e² を使った表記とすること。 ・規格化定数を求めるために以下の計算を行う。 空欄 ①~③を埋めよ。 以下の問いに答えよ。 AT THE ARE ● = 1 a 1 ²sine 00 (sines) + ²in²00²)- ressin20a2 Sy2dt = fffy2r2sin0drdodyを変数分離し,各変数ごとに定積分を行う。そ に関する定積分を実行すると (1) (B)-SIEDS F 9 に関する定積分を実行すると CARTE* ONE 31011218018 積分公式Sorne-br drを使ってrに関する定積分を実行すると 従ってC=1/√32ma5 水素様原子のシュレーディンガー方程式は 1²/10 a 1 ə rasino ao (1-²2 20 (²²0). + ər arl 2m (2) 水素原子における1s軌道の波動関数は Cer/ で与えられる。 ただしは規格化定数である。 動径分 VEAU 布関数電子が原子核から距離rの球面上に存在する確率密度) の極大値を求めよ。 HOFFE HISENSE CO 2 SMERES a sino 200+ E = 4πεr 1 2² Ze² y(r,0,9). ressin2002 4πεor である (ポテンシャルエネルギーの項で, e2がZe2になっている)。 以下の問いに答えよ。 100 Jy² dr VEEBR 3 TERENGUKS GA ここで各原子 (4) H2分子の分子軌道を水素の1s原子軌道XA XBの線形結合↓ =CaX^+ CaXで近似する。 軌道の中心はそれぞれ原子核 (H+) A, B である。 1電子エネルギーの期待値は=(2) Syd_cha+Cfa + 2CACBβ (8− 1)\1 = (x1 T4² dr C+C E = で与えられる。 ただしα, βはそれぞれクーロン積分, 共鳴積分であり、重なり積分は無視している。 ERSACERO 以下の問いに答えよ。 (1) Eが最小になる条件から永年行列式を導け。 永年行列式を解いて、 結合性軌道のエネルギーを求めよ。 1 514 r' =Zrとおいてrとp(r', 0,p)を用いたシュレディンガー方程式を書け。 水素原子の規格化された原子軌道とエネルギーをそれぞれce", Enとして, 水素様原子の1s軌道 のエネルギーと規格化された波動関数を求めよ。 答えにC, α, Enを使ってよい。 C²+C² (r,0,0) = E(r,0,9) (5) 異核2原子分子 AB の分子軌道を原子軌道XA XBの線形結合 = CAXA CBXBで近似すると, 1電子工 ネルギーの期待値は Sdr_chan+Cfap+2C^CBβ TOUCU BOUCA

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TOEIC・English Undergraduate

答え合わせの為、答えを教えて頂きたいです。 よろしくお願いします。ビジネス英語です。

Working with words 1 Complete the sentences with the words in bold. Change the form of the word in bold or add another word to it. supply 1 It's important to build good relationships with different suppliers. 2 Our supply chain begins with the manufacturer in India and ends in our UK shops. is much higher but it's transport 3 The cost of air faster. show 4 Customers from all over Europe visit our in Paris and Milan. invent 5 Every item in our photographic records of each of them. middle 6 The problem with using is that it adds to the final cost of products because we have to add on their fee. is unique, so we keep ship 7 We have a large. track 8 We use barcodes to stock coming in and out of the warehouse. made 9 All our pots are _, which makes them expensive, but our target customer doesn't want anything mass-produced. original 10 The arriving in three days. of the of the products is printed on the bottom of the box. 2 Underline the correct words in italics to complete the sentences. 1 The book is currently out of stock, but it is on / out of order, so we'll have it soon. 2 We need to stock up on / run out of headed paper. Could you put an order in? 3 I ran low on/out of ink, so I couldn't print out the report. 4 We can keep track of/ on track our order by satellite. 5 Let's stop at the next service station. We are running low/out on petrol. Business 1 Complete the phone call between Virginie, a customer, and Kevin, a call handler. Put the words in italics in the correct order. Kevin Good afternoon, you're speaking to Kevin. How can I help you? Virginie Hello, I am up/chasing/an/order chasing up an order I placed three weeks ago. Kevin account /take/I/your/details / Can please? 2 Virginie Yes. The account number is 572638. Kevin OK. If you bear with me a moment, I'll into / look/it 3 Let me see. Well, my /to / information / according it is still on order. 4 Virginie I really need to know happened /to/has/it/ what 5 Could check/me/you/it/for/out 6 ? Kevin Certainly. I'll back/you/to/hour / within/get/ the 7 Virginie Thank you. 2 Kevin calls Virginie back. Complete their conversation with the phrases from the list. put the order straight through asap charge it to was dispatched on check it out as quick as we can must have gone wrong Kevin Hello, this is Kevin from DYK calling. I've got some information about your order. Virginie Oh, thanks for calling back. So, what's happened to it? Kevin Well, we put the order straight through to the warehouse, and it 2_ the 25th. Virginie But I haven't received it yet. Kevin I'm sorry about that. Can you confirm the delivery address? Virginie We wanted it delivered to our Brussels office. Kevin Oh, something 3 It looks like it might have gone to your Paris office instead. I'll 4 straightaway. Virginie I've already been waiting three weeks. Could you just send it again 5 ? Kevin OK, no problem. We'll resend it Virginie Thank you. And please not the Paris one. the Brussels account,

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TOEIC・English Undergraduate

英語の問題です。 この答えが分かる方いらっしゃいますか?

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