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Chemistry Undergraduate

緊急です、!!!! この反応機構を矢印付きでお願いしたいです、、🥺

21:21 三 46 について | セクション 2.2 NeuroPコアの不斉合成 これ 林ピロリジン触媒存在下での9aの8への有機触媒マイケ ル付加反応とそれに続くアルデヒドの還元は、我々の以 前の報告 [26]と同様に行われ、2段階で89%の収率でアル コール7aが3:1のシン/アンチジアステレオマー混合物と して得られ、シン-7aで86%のee、 アンチ-7aで90%のee であった(図3)。 続いて、 キャンディらの条件下での 酸化Nef反応により、 87%という非常に良好な収率と16:1 のジアステレオマー比で二置換ラクトン11が得られ、 はDBU触媒による熱力学的平衡によってさらに濃縮され た。ラクトンをDIBAL-Hで還元してラクトール6aを得た 後、最初のウィッティヒ反応で開環し、アルコール12を 76%の収率で得た。塩基促進脱離副生成物13の生成を抑 制するために、徹底的な最適化が必要であったことを強 調しておくべきである。 最適化された拡張性と再現性を 備えた条件は、0℃でトルエン中の過剰量のメチル(トリ フェニルホスホニウム) 臭化物から生成したイリドの懸濁 液に6aをゆっくりと制御添加し、その後室温まで昇温す るというものである(詳細は補足情報の表S1およびS2を 参照)。 8 1.A (5mol.%), NO2 P-Nitrophenol (10 mol. %) THF, 15°C, 4 days 2. NaBH4, MeOH, 0 °C, 1 h 89% (two steps), syn/anti 3:1 OPMB 9a *NO2 + HO. HO. OPMB syn-7a anti-7a 86% ee NO2 OPMB 90% ee MePPh3Br, KHMDS Toluene 20°C to rt, 16 h NaNO2 AcOH DMF, 40°C, 16h 1.DBU (20mol.%.) HO THF, r.t., 16 h 2. DIBAL-H Toluene, 87%, trans/cis 16:1 OPMB OPMB 11 -78 to -50°C, 30 min 6a 97% (two steps) HO. HO -OPMB 12 76% スキーム3 13 9% OPMB A Ph Ph OTMS

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English Senior High

教えてください🙇🏻‍♀️

[3] 次の英文を読み, 各問いに答えなさい。 [思・判・表] (教科書 P.106~107 参照) Good morning, everyone. Today I am going to tell you about orienteering. Do you know orienteering? Maybe some of you have experienced it. You might think it's like a game in the woods, where you use a map and compass to find some flags. Well, orienteering is also a competitive sport. It started in Sweden, and is most popular in Scandinavia. In an orienteering event, ( ① )competes alone, [3] (5点x3) (1) (2) (3) wearing a running suit that protects them from the weather and the bush. At the starting line, runners start at least one minute apart. When you are told to go, you are given the map for the first time. You then use your compass and the map to find a series of points in the forest. At experienced levels, the points are often far from roads. At each point, there is an orange and white box flag. There, you punch your card. You may not go to points in the wrong order. After all of the runners have passed the finish line, the person with the fastest time in each category of sex and age range is the winner. I tried orienteering once in elementary school, but I'd like to try it someday in a competitive event. Thank you for listening. (1)( ① )にふさわしい主語を選択肢から選び, 記号で答えなさい。 ア. all people イ. each person ウ. all players (2) the loser(敗者) と反対の意味を表す語句を第二段落から探し出し, 解答欄に書きなさい。 (3)説明されている競技において、以下のア~エを進行順に並べ替えて, 3番目にくるものを記号で答えなさい。 ア. 走者達はコンパスと地図を用いて, 森の中の一連のチェックポイントをさがす。 イ. 全走者が走り終えた後, それぞれの性別や年齢層でいちばん時間が速かった人が勝者となる。 ウ. それぞれのチェックポイントには, オレンジと白の旗 (box flag)があり、そこで自分のカードにパンチで穴をあける。 エ. 走者達はスタートしていいと言われたとき, 初めて地図が渡される。

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English Senior High

下線部③を並び替えてください。という問題なんですが、どのように考えたらいいのか分かりません。 教えてください!

19 Read the passage and answer the questions. ORG OF US. udma2 to enoitelugo Imagining locations for a wedding, people think of churches, 008 00 hotel chapels, or even a beautiful beach or park somewhere. However, there are ①many more fantastic and unusual places where wedding planners can arrange the perfect day for couples 5 who want something a bit different. 0001 Located deep underground, the National Showcaves Centre for Wales can provide a stunning background to a wedding ceremony. There is a huge section in the caves called the "Dome of St. Paul's," which includes two waterfalls flowing into a large lake. 10 The cave's natural and romantic setting ②could make a wedding truly special. 009 008 00% QHints aros chapel [tfæpǝl] 礼拝堂, チャペル the the ocean. stunning [stániŋ] とてもすばらしい cave [kéiv] than waterfall [wó:tǝrfò:]] 008 00 spectacular [spektækjulǝr] 壮観な As some people might not want to marry in a cave, a company 008 in New Zealand offers a wedding ceremony in a spectacular outdoor setting. The company will fly couples and their guests by 15 helicopter to the top of a mountain. Looking at the amazing fuquq ow! T panorama of mountains, lakes and rivers, lovers ③[ will become might their wedding / how / easily imagine ] one of the most memorable days of their lives.nd 20 a (S) atos Even more adventurous couples can get married underwater. 20 Putting on scuba gear, the couples descend to a depth of 15 gear [giǝr] meters in the sea off the coast of Trang province in Thailand. Of course, exchanging wedding vows underwater is difficult, so they T 25 need to use a series of diving hand signals, ending with an "OK" sign to indicate "I do." As well as these locations, there are thousands of other places around the world that can offer lovers an alternative to the tradition of walking down the aisle. Perhaps f future weddings will be held in space, on the moon, or even on Mars. (269 words) 『リーディングに役立つ英文法-ENGLISH CHALLENGER」 Kyoko Okamoto, Benedict Rowlett Aya Kinoshita, Sara Ellis*** descend [disénd] b off the coast of ~ ~沖で Trang province in Thailand タイのトラン県 vow [vȧu]) pninatai.l aisle 通路 onsiquis el lliw omi) indW (S)

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