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Chemistry Senior High

問4b 解答の別解について 2枚目の線を引いてあるところが分かりません 上澄み溶液って40mlから変化していないのですか?

化学 ・沈殿ⅡI- A (白色) 4 次の文章を読み, 後の問い (a~c) に答えよ。 KI, K2CO3, K2SO4, K2CrO4 を水に溶かして得られる水溶液 ×10.0mLに次 の操作 Ⅰ~Ⅲを行った。 操作 Ⅰ Ⅰ とろ液に分離した。 沈殿Iには化合物A (白色), 化合物 B (白色), 化合 水溶液 X に BaCl 水溶液を十分加えたのち生じた沈殿をろ過し,沈殿 物 C (黄色) が含まれていた。 操作ⅡⅠ 沈殿 Ⅰ に アを十分加えると, CO2 が発生して沈殿Ⅰの一部が溶 解した。 溶け残った沈殿ⅡI をろ過し、ろ液ⅡI を得た。 沈殿Ⅱには, A (白色) が含まれていた。 また, ろ液ⅡⅠIは赤橙色であった。 これは, CrO²が Cr2O7に変化したためである。 操作Ⅲろ液に イ D(白色), 化合物E(黄色) が含まれていた。 TOEIC) BaSO4 操作ⅡI を加えたところ, 沈殿が生じた。 沈殿Ⅲには化合物 -沈殿Ⅰ Bacro4 A, B, C (白色) (白色) (黄色) CO2 発生 ア 水溶液X- I, CO32-, SO4²-, CrO4², K+ 操作Ⅰ ろ液ⅡI (赤橙色) 図1 操作 Ⅰ~Ⅲの流れ - 112- BaCl2 水溶液 -沈殿Ⅲ D, (白色) 液Ⅰ |操作ⅢII E (黄色) イ a 操作ⅡIで加えた試薬「 れか。 最も適当なものを、次の①~⑥のうちから一つ選べ。 ① 12CO30 ② ⑤ (6) ア NaOH水溶液 NaOH水溶液 AgNO3 水溶液 AgNO3 水溶液 塩酸 塩酸 ① 4.0×10-4 ④ 3.2×10-3 ア と、操作で加えた試薬 0.1X Bacos そして↓ b 操作ⅡIで発生したCO2 の全量を, 0.100 mol/LのBa(OH)2 水溶液 40.0mL に吸収させると沈殿が生じた。上澄み液を100mL はかりとり、未反応の + Ba(OH)2を, 0.100 mol/Lの塩酸で滴定したところ 18.0mL を要した。 水溶液 ×10.0mL を得るために水に溶かした K2CO3 の物質量は何mol か。 最も適当 な数値を、次の①~⑥のうちから一つ選べ。 18 omol 74% 2xn+0.1x 100% イ AgNO3 水溶液 塩酸 NaOH 水溶液 塩酸 NaOH水溶液 AgNO3 水溶液 0.009 2500000 のmodをn(mmとする。 CO2は2価の酸 18 7000 ② 8.0×10-4 3.6×10-3 x+ = 2x 01x CO2 18 イ + 40⁰ の組合せはど 17 Ba(OH)2 0.004 0.004-2 0.1x 化学 ③ 1.8×10-3 ⑥6.2×10-3 Bacos FRA 1.8 3 10000+1.8=4 - 113- 1000 20000.1=0.48.10 1000 212 -0.004 1000x~ 2.2

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English Senior High

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4 eehaupbsorl elstog 空欄にあてはまるものを (A)~(D) の中から選んで記号を書きましょう。 rinom soon tundA (8) 1. My first of Toronto was very positive. (A) impressed (B) impressing (C)impressive (D) impression swdua vd oo visuay 1 (5) 3. 2. The special equipment was (A) originally (B) origin (C) original (D) originality 4. The manufacturer (A) produces vaboj alriemriserter prind soinom bib vilW..t A teacher's class. Sum ob incinu vertone (A) friendship (B) friendlily (C) friendly (D) friendliness Autoledad blow approach makes new students feel comfortable in their new es new students fee (B) has produced shwob trand enirkham y 5. It is necessary that the applicant 8. Would you mind (A) open made for those who have mobility problems. mismo2( bloo out a'fariT (8) Of(0) tripim men (8) TV sets in developing countries ten years ago. (D) has been produced (C) produced (A) fill (B) filled (C) fills (D) would fill 6. Tomoko invited me to see the musical with (A) she (C) (B) heraners 10. Is there anyone (A)whom blueWF Tesy jasi cio 7. The CEO by the charity foundation to speak at their annual conference, but he had to decline the request because of a scheduling conflict. (A) asked (D) had been asking (B) was asked (C) has asked 9. The meeting will be held (A) in dar out the form before the job interview. toy bollit need cen (A) admun orong olidam ym e'evgH (8) Jeneves need even ment (2) eldabil opening prupiolansi (B) whose blow reiwi at sol no (D) herself them. the window for me? vietne.m (C) to open (D) to be opening Houp (0) (B) on (C) for (D) at nismen (0) Meason (2) gribnstalue (8) 10:30 in the conference room. is against this alternative proposal? (D) which m) boysin .GP .er Deda briced OS eldialval (A) 11. Tim is as as Linda. (A) more intelligent (B) intelligent (C) less intelligent (D) better intelligent for storage. (A) designated (B) detained (C) reciprocated (D) signified 12. According to the proposal, a large block of rooms in the east wing of the new building will be

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English Senior High

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4 eehaupbsorl elstog 空欄にあてはまるものを (A)~(D) の中から選んで記号を書きましょう。 rinom soon tundA (8) 1. My first of Toronto was very positive. (A) impressed (B) impressing (C)impressive (D) impression swdua vd oo visuay 1 (5) 3. 2. The special equipment was (A) originally (B) origin (C) original (D) originality 4. The manufacturer (A) produces vaboj alriemriserter prind soinom bib vilW..t A teacher's class. Sum ob incinu vertone (A) friendship (B) friendlily (C) friendly (D) friendliness Autoledad blow approach makes new students feel comfortable in their new es new students fee (B) has produced shwob trand enirkham y 5. It is necessary that the applicant 8. Would you mind (A) open made for those who have mobility problems. mismo2( bloo out a'fariT (8) Of(0) tripim men (8) TV sets in developing countries ten years ago. (D) has been produced (C) produced (A) fill (B) filled (C) fills (D) would fill 6. Tomoko invited me to see the musical with (A) she (C) (B) heraners 10. Is there anyone (A)whom blueWF Tesy jasi cio 7. The CEO by the charity foundation to speak at their annual conference, but he had to decline the request because of a scheduling conflict. (A) asked (D) had been asking (B) was asked (C) has asked 9. The meeting will be held (A) in dar out the form before the job interview. toy bollit need cen (A) admun orong olidam ym e'evgH (8) Jeneves need even ment (2) eldabil opening prupiolansi (B) whose blow reiwi at sol no (D) herself them. the window for me? vietne.m (C) to open (D) to be opening Houp (0) (B) on (C) for (D) at nismen (0) Meason (2) gribnstalue (8) 10:30 in the conference room. is against this alternative proposal? (D) which m) boysin .GP .er Deda briced OS eldialval (A) 11. Tim is as as Linda. (A) more intelligent (B) intelligent (C) less intelligent (D) better intelligent for storage. (A) designated (B) detained (C) reciprocated (D) signified 12. According to the proposal, a large block of rooms in the east wing of the new building will be

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