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化学 大学生・専門学校生・社会人

緊急です、!!!! この反応機構を矢印付きでお願いしたいです、、🥺

21:21 三 46 について | セクション 2.2 NeuroPコアの不斉合成 これ 林ピロリジン触媒存在下での9aの8への有機触媒マイケ ル付加反応とそれに続くアルデヒドの還元は、我々の以 前の報告 [26]と同様に行われ、2段階で89%の収率でアル コール7aが3:1のシン/アンチジアステレオマー混合物と して得られ、シン-7aで86%のee、 アンチ-7aで90%のee であった(図3)。 続いて、 キャンディらの条件下での 酸化Nef反応により、 87%という非常に良好な収率と16:1 のジアステレオマー比で二置換ラクトン11が得られ、 はDBU触媒による熱力学的平衡によってさらに濃縮され た。ラクトンをDIBAL-Hで還元してラクトール6aを得た 後、最初のウィッティヒ反応で開環し、アルコール12を 76%の収率で得た。塩基促進脱離副生成物13の生成を抑 制するために、徹底的な最適化が必要であったことを強 調しておくべきである。 最適化された拡張性と再現性を 備えた条件は、0℃でトルエン中の過剰量のメチル(トリ フェニルホスホニウム) 臭化物から生成したイリドの懸濁 液に6aをゆっくりと制御添加し、その後室温まで昇温す るというものである(詳細は補足情報の表S1およびS2を 参照)。 8 1.A (5mol.%), NO2 P-Nitrophenol (10 mol. %) THF, 15°C, 4 days 2. NaBH4, MeOH, 0 °C, 1 h 89% (two steps), syn/anti 3:1 OPMB 9a *NO2 + HO. HO. OPMB syn-7a anti-7a 86% ee NO2 OPMB 90% ee MePPh3Br, KHMDS Toluene 20°C to rt, 16 h NaNO2 AcOH DMF, 40°C, 16h 1.DBU (20mol.%.) HO THF, r.t., 16 h 2. DIBAL-H Toluene, 87%, trans/cis 16:1 OPMB OPMB 11 -78 to -50°C, 30 min 6a 97% (two steps) HO. HO -OPMB 12 76% スキーム3 13 9% OPMB A Ph Ph OTMS

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英語 高校生

4行目の42パーセントがなぜ42になるのか分かりません。教えてください。

6 グラフと英文について問いに答えなさい。もの K There has been growth in the sales of computer and video game units in the United States for the past 12 years. Perhaps the largest growth was between [ ] and [ ], when the sales of computer and video game units increased about 42 percent. After 1998, there has been a steady increase in the sales except in ts sold than in []. In 2006, the US computer were fewer units [], when there were to and video game software sales grew six percent. none od oals U.S. Computer and Video Game DOLLAR Sales Growth orond noologa ORA 8.0 7.0 vien.n 7.0 -7.4 7.1 7.0 s or saoby 6.0 5.0 14.0 13.0 2.6-- 2.0 1.0 速読問題 43NTO 3.7. mouter and vi 4.8 computer STR. STEST 5.5-5.6... 6.1 【目標時間 5分 】 Talouno A-43 (関東学院大) (各4点) SMOO simsbine 320.0 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 0.0 .noitonitys asgougnal ) Jonitzs „299sugnal artito e Year oqe sdb 10 Ilse Tho bollbl ti jeste sdo tir 1. 本文の空所に入る年の最も適切な順番を示した組み合わせを1つ選びなさい。 idal ① 1996-1997-2004-2005 regorin 2 1996 - 1997 - 2005 - 2004 3 1997 - 1998 - 2004 - 2005 to nl241997 - 1998 - 2005 - 2004 gablesqa gnirlismoe orbi xim yam yod 10 mi 10 ogsugnal assinoloo 2. 本文の内容に一致するように、次の質問に対する最も適切な答えを1つ選びなさい。 no senso que parve pegeuren enorget to sum gels Sie wer From this article, how high would the bar for 2006 for the total number of W morb 100 98 10qa amepad slenIA video games be? Approximately the same height as 2005. 2 Shorter than 2005. 3 Taller than 2005. 033ghel to vio 4 tell. It is impossible to go this fod Bhixe ed or go sew tadi sesugn tell. a los ama zagsugnal sviten od on T srit ni nosloga asw dojdw.raimoƆ bollas syaugmel och tarb bisa quong 002 【2 スニング なさい。英文は2度読まれます。 Fived

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英語 中学生

これの(②)に一語を文章から抜き出していれるんですけど、quickはだめですか? 答えはearlyでした。

When I first moved to Japan, my new life was like an adventure, and full of surprises. Ive forgotten a lot of small things, but I'll never forget the first party I gave. 1was teaching English at a university in Japan. I decided to have a party for some Japanese students at my apartment which was near the school. The party was at 7:00. I was rushing to get ready, cleaning the room, checking the food, and so on. And finally at about 6:45, I was about to take a quick shower and get dressed. Perfect timing, I thought. But just then, the doorbell rang. The students, in one big group, were already at my door! In America nobody comes early, and in fact, most people come a little late on purpose, usually alone or in pairs. We call Oit being “fashionably late." I had to ask them to wait outside for about 15 minutes. “The party starts at 7:00!" I said, This was a real life lesson for them and for me about cultural differences. They learned they should not come to my parties ( ② ) again, and I learned I should be ready a little (2 )just.in.case. So at 7:00, everyone came in, with my second surprise. ③They showered me with all kinds of presents! I was happy to get so many presents, of course, but I really didn' t want them to come together. I was very busy because I had to find vases for the flowers, bowls for the snacks, and try to say Thank you' for their gifts. People usually take something likea bottle of wine to an American-style party. But I felt. more. appreciated by my_guests in Japan. It was more like my birthday or Christmas than a simple homeparty. FinallyI sat on the sofa and talked with them. Everyone was having a good time. Though I have lived in Japan for more than ten years, I m still surprised at many things. Life is full of surprises.

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英語 高校生

この問題の解説で大切な部分は何処か教えて欲しいです🙏

Part 2 Reading 実 践/演習 次の英文を読んで,a~eについて本文の内容と一致するものを①~③の中から1つずつ選びなさ loog sui 1 い。 I have to make a speech in the next Englishi class. I decided to talk about my own town, so I started looking for good stories about it. First I used the Internet and entered the name of the town. I thought I could get a lot of good information very quickly, but I couldn't. There were some homepages about my town, but I found some were wrong and others were the stories we all already knew. Next I went to the library. I tried to find useful books. but again I couldn't. I asked the He said, “Sorry, we have few, man at the counter if there were any books about the town. but what do you want to know ?” So I explained to him about my speech. Then he said, 1 can tell you all the things I know about our town.”. He has lived here for sixty years and knows a lot about the town. Ilearned many things from him. I will be able to give an interesting speech. la 1elg la 0a speech 出 6angalaateland oaery ご愛a.I began to collect {2 the information about my town. 人丈さ 具 ふこ Sn aF13 an English class の d e 言0no woRO時 hatuhdy s 下ab. I got{ 2 a lot of } useful stories from the Internet.dh 内 が enjoyed tal③ good oticO ( heis lem in his garden. "They often made jokes with each other しhish 液 O1"Do you know about my speech ?"npdea Shis ffc.I said to the man in the library, {2 “Do you know about the town ?" lske lODo you have any books about the town ?" byでda 戻りでFO he had lived in the town for a long time. ad. The man knew about the town well because { 2 he worked for the library. by plane. 土制効 人(O the Internet. 3 he learned many things from the books. パーモーエニ e. I will make a good speech thanks to { 2 the books in the library. で ドンに行 ③ the man in the library. れ ヒント thanks to ~は 「~のおかげで」。良いスピーチができそうなのは何(誰) のおかげ? おます で い場 の 下 ム ま合 stwals

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