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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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生物 大学生・専門学校生・社会人

至急お願いいたします🚨 生物の質問です。 ミトコンドリアの経路についての説明だと思うのですが、電子オーバーフローモデルと電子分布モデルの違いを教えていただきたいです。 また、どういう仕組みなのか、何故このように電子が流れるのかも教えていただきたいです。 UQ poolはユ... 続きを読む

(A) Electron overflow model (considered out-of-date) Alt UQ pool Alternative oxidase inactive. Alt No alternative pathway activity Cytochrome pathway unsaturated Cyt (B) Electron distribution model (reflects current thinking) UQ pool Cyt Alternative pathway active Cytochrome pathway saturated Alt Alternative oxidase active Alt UQ pool Cyt Cyt Figure 14.33 Two models for regulation of electron flow through the alternative oxidase. (A) In the electron overflow model, no appreciable electron transfer through the alternative pathway takes place until electron flow through the cytochrome pathway is at or near satu- ration. This could result from the effects of respirato- ry control, if the rate of mitochondrial ATP produc- tion exceeds its rate of utilization in the cytosol, or from some externally imposed stress, such as low temperature. Under such circumstances, the UQ pool becomes sufficiently reduced to allow electrons to flow through the alternative oxidase, the latter re- quiring that the UQ pool be 40% to 60% reduced to attain significant activity. (B) In the electron distribu- tion model, the alternative and cytochrome path- ways both show significant activity at low levels of UQ pool reduction, and electrons are distributed be- tween the two pathways on the basis of the relative activities of each pathway. The activity of the alter- native oxidase under these circumstances is thought to be regulated by the action of a-keto acids and by reduction/oxidation of the intermolecular disulfide bond, as well as by additional regulatory mecha- nisms not yet characterized.

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英語 高校生

全文訳お願いします!

4 20 科学 420 words Chapter 1 The recipe for making any creature is written in its DNA. So last year, when 1-1 geneticists* published the near-complete DNA sequence of the long-extinct woolly mammoth, there was much speculation about whether we could bring this giant creature back to life. 5 東京理科大学 Creating a living, breathing creature from a genome* sequence that exists only in a computer's memory is not possible right now. But someone someday is sure to try it, predicts Stephan Schuster, a molecular biologist at Pennsylvania State University and a driving force behind the mammoth genome project. So besides the mammoth, what other extinct beasts might we bring back to life? Well, 12 10 it is only going to be possible with creatures for which we can recover a complete genome Without one, there is no chance. And usually when a creature dies, the (1) - DNA in any flesh left untouched is soon destroyed as it is attacked by sunshine and bacteria. sequence. There are, however, some circumstances in which DNA can be preserved. If your 15 specimen froze to death in an icy wasteland such as Siberia, or died in a dark cave or a really dry region, for instance, then the probability of finding some intact stretches of DNA is much higher. Even in ideal conditions, though, no genetic information is likely to survive more than a million years. - so dinosaurs are out and only much younger remains are likely to yield good-quality DNA. "It's really only worth studying specimens that are less than 100,000 years old," says Schuster. The genomes of several extinct species besides the mammoth are already being sequenced, but turning these into living creatures will not be easy. "It's hard to say that something will never ever be possible," says Svante Pääbo of the Max Planck Institute 25 for Evolutionary Anthropology in Germany, "but it would require technologies so far removed from what we currently have that I cannot imagine how it would be done." But then (3) 50 years ago, who would have believed we would now be able to read the instructions for making humans, fix inherited diseases, clone mammals and be close to creating artificial life? Assuming that we will develop the necessary technology, we have 30 selected ten extinct creatures that might one day be resurrected. Our choice is based not just on practicality, but also on each animal's "charisma" - just how exciting the prospect of resurrecting these animals is. 1-3

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英語 高校生

1枚目が問題文、2枚目の(B)のカッコに下の選択肢から当てはまる英単語を選ぶ問題です。 解答お願いしますm(*_ _)m

次の英文(A)の内容を要約して英文(B)を完成させるには、③~ の (o)の中にはどの語 句が入りますか。もっとも適当なものを①~4の中から1つずつ選びなさい。 auon which A job interview can be one of the most stressful experiences you ll ever nave, especially the first one. What should you expect when you ve been invited for an interview? While it's impossible to *"predict exactly what you will be asked, many Japanese companies take a rather *"formulaic approach. It would be in your best interest to become familiar with this approach. in 2020 P BSCamaG Use of First, you will likely be asked to introduce yourself. It's a good idea to keep your answer fairly short and to the point, without getting into too much detail. In addition, you will almost certainly be asked why you want to work for the company. It's very important that you prepare carefully for this question in advance. Your answer representS an op opportunity to make a strong impression on the interviewers by showing your in-depth e Cop knowledge of the company and stating clearly why the company best fits your qualifications, skills, and long-term goals, You should also be prepared to discuss your strengths and weaknesses. You're advised to **emphasize your strengths without sounding *overconfident. If you're asked about your weaknesses, mention one that isn't related to the pe0 position. For example, admitting that you're not a good public speaker probably won't hurt your chances of being hired as a software engineer. At the end of the interview, you may be asked if you have any questions. It's a good idea to prepare some questions in advance in case this opportunity arises. Questions such as career advancement opportunities questions. Finally, end the interview in a polite manner by standing, stating that it was an honor meeting everyone, and bowing. If all goes well, you'll hear from them again soon. Good luck! 295d sldsaus *formulaic:型にはまったesb je9108) and working hours are suitable meoもの never make thisworld peaceful *predict:予測する *emphasize:強調する *overconfident:自信過剰な motivna 【令和3年度 第66回 1級]

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英語 中学生

教えてください!

Rules in the School Library Grammar Focus Time and Place, Inversion We use phrases with prepositions and adverbs when we describe time and place. They are usually placed at the end of a clause or sentence. However, some emphatic expressions should be placed at the beginning of aclause or sentence and need to have an unusual structure, called inversion. Choose a phrase from the box below to complete each of the following sentences. Use a capital letter to begin the first word of each sentence. 1. The blueprints for the new buildingare on hold ( 2. A radical change in the formula fora new drug will take place ( 3. The scientific program has aired continuously ( ) did scientists decide that air, earth and fire were not really elements at all. 5. The Earth pulls on all objects with a force of gravity ( 6. My adviser will have been teaching for forty years ( 7. Most of the undergraduate students in the Faculty of Global Studies study abroad ( 8. All the classes during the first period are required to start ( ) were wriggling angleworms. 10. Lithium batteries are prohibited to be sent ( by air in many countries b. bythe end of the school year a. at the beginning of the year C。 d. until the end of October e. not until the eighteenth century f. since April 5, 2009, on the QBS Television Network g. during their second year h. under piles of leaves i. downward, that is, toward the center of the Earth on time, at 9:00 in the morning j.

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