-
-
第â
¡ç« ç©è³ªã®å€å
ãã
(3) ã¯ããã«å ããå¡©é
žäžã®å¡©åæ°ŽçŽ ã®ç©è³ªéã¯ã
200
1000
-L=8.0Ã10mol
ã«ããŒ
ããŠã
(20 倧éªå·¥
10l/Lã®æ°Žé
ž
ã®äœç© [L] (
âã¯ã©ã®ãã
1 0.1mol
cde)ã«äŒŽã£ãŠãè±é»çã®æããã¯
. åå¿
NY äžåç¹b ãšäžåç¹dãç¥ãããã«ãæç€ºè¬ã¯ãã§ããŒã«ãã¿ã¬
ã³ãžã®ã©ã¡ãã䜿çšããã°ãããã ããããçç±ãšãšãã«çããã
(10 ä¿¡å·äºº
163. æ··åç©ã®äžåâ çé
žã«ã«ã·ãŠã ã匷ç±ãããšãäžéšãäºé
žåççŽ ãšé
žåã«ã«ã·ãŠã
ã«åè§£ããã ãã®åŸã以äžã®å®éšãè¡ã, çé
žã«ã«ã·ãŠã ã®åè§£å²åã調ã¹ãã
ãšããã åºäœã¯æ°äœãçºçããªããå®å
šã«æº¶è§£ãããåŸãããæº¶æ¶²ãæ°Žã§ããããŠæ£ç¢º
çé
žã«ã«ã·ãŠã ã®å ç±åŸã«æ®ã£ãåºäœ2.06g ã« 0.40mol/Lã®å¡©é
ž200mL ãå ãã
250mLã®æº¶æ¶²ã調補ããã ãã®åžé溶液ã®25.0mLã0.10mol/Lã®æ°Žé
žåãããª
ãŠã æ°Žæº¶æ¶²ã§æ»Žå®ãããšããã äžåã«ã¯æ°Žé
žåãããªãŠã 氎溶液ã 30.0mLå¿
èŠã§ãã£
ãã æ¬¡ã®ååãã«çããã ãã ã, (2) (4) ã«ã€ããŠã¯æå¹æ°å2æ¡ãšããã
(1) çé
žã«ã«ã·ãŠã ããã³é
žåã«ã«ã·ãŠã ãšå¡©é
žãšã®åå¿ãååŠåå¿åŒã§ç€ºãã
Q äžç·éšã§èª¿è£œããæº¶æ¶²äžã®å¡©åæ°ŽçŽ ã®æ¿åºŠã¯äœmol/L ãã
(ã¿ åºäœè©Šæ 2.06g ãæº¶è§£ããã®ã«æ¶è²»ãããå¡©åæ°ŽçŽ ã¯äœmolãã
ã¢ã³
ããªãŠã
164. äºæ®µéæ»Žå®æ°Žé
žåãããªãŠã ãšçé
žãããªãŠã ã®æ··å氎溶液äžã®ããããã®æ¿åºŠ
(17 京éœåºç«å€§ æ¹ )
床ã¯åã
å¿
èŠãª
çé
žã«ã«ã·ãŠã ã®ãã¡å ç±ã«ãã£ãŠåè§£ããå²å [%]ãæ±ããã
å®éš
æ¬ç© [L]
1
(L
äžæŽå€§ æ¹
ãæ±ºãããã,次ã®å®éšãè¡ã£ãã äžã®ååãã«çããã
æ°Žé
žåãããªãŠã ãšçé
žãããªãŠã ãå«ã溶液ã(ã¢)ã§20.0mL ã¯ããåã ã³
ãã«ã«ããŒã«ãŒã«å
¥ããã 0.100mol/Lã®åžå¡©é
žã(ã€)ã«å
¥ã,ãã§ããŒã«ãã¿
ã¬ã€ã³ãçšããŠæ»Žå®ãããšãã, 第1äžåç¹ãŸã§16.0mLãèŠããã ãã®åŸ,
(ãŠ)ãçšããŠæ»Žå®ãç¶ãããšç¬¬2äžåç¹ãŸã§ããã«2.8mLãèŠããã
(ã¢)~ (ãŠ) ã«é©åãªåšå
·ã»è©Šè¬ã®åç§°ãå
¥ããã
0.40mol/Lx
åå¿ããã«æ®ã£ãå¡©åæ°ŽçŽ ã®ç©è³ªéã¯,(2)ãã,
250
0.12mol/Lx.
1000 L=3.0Ã10-2 mol
ãããã£ãŠã2.06gã®åºäœãšã®åå¿ã§æ¶è²»ãããå¡©åæ°ŽçŽ ã®ç©è³ªéã¯ã
8.0Ã10-mol-3.0Ã10mol=5.0Ã10-mol
(4) 2.06gã®åºäœã«å«ãŸããçé
žã«ã«ã·ãŠã CaCO3 (ã¢ã«è³ªé100
æ°Žé
žåg/mol)ã®ç©è³ªéã x [mol] é
žåã«ã«ã·ãŠã CaO (ã¢ã«è³ªé56g/mol)ã®
ã§ã¯2åã«
om
æç€ºè¬
åã§æ°Žæº¶
BaSO
(2) äžç·éšâ ,â¡ã§,åæç€ºè¬ã®å€è²ã®å®äºãŸã§ã«ããã£ãå€åãååŠåå¿åŒã§ç€ºãã
(3)ãã®æ··å氎溶液äžã®æ°Žé
žåãããªãŠã ããã³çé
žãããªãŠã ã®æ¿åºŠã¯ããããäœ
mol/L ãã æå¹æ°å2æ¡ã§çããã
ããŠããã
(19 ä¿¡å·å€§)
HOM
93
ç©è³ªéã y[mol] ãšãããš,
100g/molxx[mol]+56g/molxy[mol]=2.06g...
â¡â¢ã®ååŠåå¿åŒã®ä¿æ°ãã, 1mol ã® CaCO3, 1molã®CaOã®
ãããã2molã®å¡©åæ°ŽçŽ HCI ãšåå¿ããã®ã§, (3) ãã
(x+y) [mol]Ã2=5.0Ã10-mol
⣠â€åŒãè§£ããš, x=0.015mol, y=0.010mol ãšãªãã
â€
â ã®åå¿åŒããã1molã®CaCO3 ã®åè§£ã§1molã®CaO ãçããã®ã§ã
å ç±ã«ãã£ãŠåè§£ãã CaCO3 㯠CaO ãšåã 0.010mol ãšãªããããã
ã£ãŠã¯ããã® CaCO3ã®ãã¡åè§£ããå²å [%] ã¯,
0.010mol
x100=40
ã¯ããã®å¡©åæ°ŽçŽ ã®ç©è³ª
éãããåå¿ããã«æ®ã£
ãå¡©åæ°ŽçŽ ã®ç©è³ªéãåŒ
ããŠæ±ããã
ãã
0.015mol+0.010mol
164. äºæ®µé滎å®ã»
è§£ç 1 ) ããŒã«ãããã (ã€) ãã¥ã¬ãã (ãŠ) ã¡ãã«ãª
ã¬ã³ãž
(2) â NaOH+HCI
Na2CO3+HCI
NaCl+H2O
NaHCO3+NaCl
â¡ NaHCO3 + HCI NaCl + H2O+CO2
(3) NaOH 6.6Ã10mol/L Na2CO31.4Ã10-2mol/L
解説 (1) (ã¢) äžå®äœç©ã®æ°Žæº¶æ¶²ãã¯ããåãã«ã¯, ããŒã«ããã
ããçšããã
Cao (ã€) ã³ãã«ã«ããŒã«ãŒäžã®æ··å氎溶液ã«åžå¡©é
žã滎äžããéã«çšãã
åšå
·ã¯ãã¥ã¬ããã§ãã
(ãŠ) 第2äžåç¹ã¯é
žæ§åŽã«ãããããå€è²åãé
žæ§åŽã«ããã¡ãã«ãª
ã¬ã³ãžãçšããã
(2) (3) æ··åæ°Žæº¶æ¶²äžã®NaOHã®ã¢ã«æ¿åºŠã x [mol/L], Na2CO3ã®
ã¢ã«æ¿åºŠãy [mol/L] ãšããã
äžç·éšâ ã§, ãã§ããŒã«ãã¿ã¬ã€ã³ãæç€ºè¬ãšããŠè©Šææ°Žæº¶æ¶²ãå¡©é
žã§
滎å®ãããšãæç€ºè¬ã®å€è²ãŸã§ã«æ¬¡ã®2ã€ã®å€åããããã
â第1äžåç¹ã¯å¡©åºæ§åŽ
ã«ãããæç€ºè¬ãšããŠã
ã§ããŒã«ãã¿ã¬ã€ã³ãçš
ããããã
è§£ç (1) CaCO3+2HCI
163. æ··åç©ã®äžåã»ã»
CaO+2HCI â CaClâ+HâO
(2)0.12mol/L (3)5.0Ã10-mol (4) 40%
CO.HD
CaCl2+H2O + CO2
解説 (1) çé
žã«ã«ã·ãŠã CaCO ãå ç±ãããšæ¬¡ã®åå¿ãããã,
äºé
žåççŽ CO2 ã®çºçãšãšãã«é
žåã«ã«ã·ãŠã CaOã®åºäœãçæããã
...1
CaCO â CaO+CO,
ãããã£ãŠ,å ç±åŸã®åºäœã«ã¯ã æªåå¿ã®CaCO ãš CaO ãå«ãŸã,ã
ãã«å¡©é
žãå ãããšããããæ¬¡ã®ããã«åå¿ããã
CaCO3
åå¿åŒã¯, ãŸãšã
ãã«å¥ã
ã«ç€ºãã
CaCO3+2HCl â CaCl2+H2O + CO2 
â¡
â¡äžç·éšã§èª¿è£œãã
CaO+2HCl â CaCl2+H,O
...â¢
250mLã®ãã¡ã25
(2) äžç·éšã§èª¿è£œããæº¶æ¶²äžã®å¡©åæ°ŽçŽ HCI ã®æ¿åºŠã c[mol/L] ãšã
ããš,ãã®æº¶æ¶²25.0mLã®äžåã«0.10mol/L æ°Žé
žåãããªãŠã 氎溶液
ãäžå滎å®ã«äœ¿çšããŠ
ãã®ã§,ãããã®
25.0
1000
c=0.12mol/L
30.0mLå¿
èŠã§ãã£ãã®ã§ã次åŒãæãç«ã€ã
1Xc[mol/L]Ã L=1Ã0.10mol/Lx
ã®æ¿åºŠãc [mol/L]1
30.0
L
1000
ãã
NaOH+HCI NaCl + H2O
Na2CO3+HCI
NaHCO3+NaCl
... (a)
...(b)
ãããã£ãŠ, Na2CO3 ããã³ NaOHã®ç©è³ªéãšHCI ã®ç©è³ªéã®éã«æ¬¡
åŒãæç«ããã
x (mol/L) X-
20.0
1000
20.0
-L+y[mol/L] x-
1000
-L=0.100mol/Lx16.01
1000
ã»ã»ã» (ã¢)