（4）で、3枚目の解答の左ページの下から右ページの上にかけて書かれている等電点での電荷の関係と式の意味がわかりません。 教えてくださったら嬉しいです。

C (分子量: M) 0.260 g 版物の質量 生成物D (分子量: M+14.0) 生成物E (分子量: M+28.0) 6.105 g 7.104g 0.295 g 0.944g (1) 高分子試料 ABおよび生成物 C・D・Eのうちフェーリング液に対して還元性を 示すものをすべて、化合物の記号で答えよ。ただし、下線部(i)の事実に注意せよ。 (2) 下線部(i)の枝分かれ率を試料Aと試料Bで比べると(Aの枝分かれ率): (B の枝分 かれ率) =1xであった。xの値を有効数字2桁で答えよ。 241. <アミノ酸の電離平衡〉 中性アミノ酸であるアラニンは式① のように二段階の電離をする。 〔19 東京慈恵医大 ] CH3 5.0×10 CH3 2010-10 CH3 2 K K₁₂ *H3N-C-COOH Hat *H3N-C-COO + H+ H2N-C-COO +2H+ H 式① 値が大きいほど電離する COOH CH2 Hストル ここで,K, および K2 は第一電離および第二電離の電離定数である。 また、酸性アミノ酸であるグルタミン酸の構造式は図1で表される。 グルタミン酸の電離を式①と同様に表す時、グルタミン酸では不斉炭素 原子に結合しているカルボキシ基の電離が最も大きな電離定数を有する ことに注意する。そのため、グルタミン酸の電離は式 ②のように表される。 CH2 H2N-C-COOH H (図1) Ki [イ + H+ +2H+ エ +3H+ 式 ① ② で表されるように, アミノ酸を水溶液に溶 かすとそのpH に応じて電離状態が変化する。 ここで, アミノ酸内の電荷の総和が全体として0になる pH を等 電点という。図2のようにろ紙上にアミノ酸を滴下して 電流を流すと, 緩衝液(緩衝溶液)のpHに応じてアミノ 酸がろ紙上を移動する。 緩衝液を染み込ませたろ紙 ろ紙の中心を示す線 陰極側 |陽極側 電流を流す前の アミノ酸の位置 (図2) 以下の設問に答えよ。 ただし, (1) (4) (5) Ⅱの解答は四捨五入により小数第1位まで 示せ。 [HI]をもとめる ①式①において,アラニンの第一電離と第二電離の電離定数K, と K2 をそれぞれ 5.0×10 - mol/L, 2.0×10-1mol/L とする。アラニンの等電点を求めよ。 (2) アラニンの緩衝作用は等電点に近づくにつれて大きくなるか,それとも小さくなる

読みましたが、全体的に理解出来ません。英語で理解出来なかったので多分、全文和訳しても理解出来ません。 なので、この写真に載っていることを分かりやすく教えていただきたいです🙇🏻‍♀️

Free energy changes determine if a reaction is endothermic or exothermic. Processes in nature are driven in two directions: toward least MAIN IDEA enthalpy and toward greatest entropy. When these two oppose each other, the dominant factor determines th direction of change. As a way to predict which factor will dominate fora given system, a function has been defined to relate the enthalpy and entropy factors at a given temperature tropy and constant pressure. This combined enthalpy-entropy function is callepd t free energy, G, of the system; it is also called Gibbs free energy. This function simultaneously assesses the tendencies for enthalpy and entropy to change. Natural processes proceed in the direction that lowersthefree energy of a system. Only the change in free energy can be measured. It can be defined in terms of changes in enthalpy and entropy. At a constant pressure and temperature, the free-energy change, AG, of a system is defined as the difference between the change in enthalpy, AH, and the product of the Kelvin temperature and the entropy change, which is defined as TAS. Free Energy Change AGO= AH°- TASO Note that this expression is for substances in their standard states. The product TAS and the quantities AG and AHhave the same umor usually kJ. The units of AS for use in this equation are usually N If AG<0, the reaction is spontaneous. AH and AS in the free-energy equation can have positive or negative values. This leads to four possible combinations of terms.

【英語ですみません】最後の12番は何を書いたら良いのでしょうか…？ Video C の実験では、aqueous solution にlead(ii) nitrate, aqueous solution にPottasium iodide を入れていました。 2KI (aq)... 続きを読む

With lead (I) nitrate solution. This precipitation reaction produces a bright yellow solid. (point values in parentheses) Part 1: 1. Copy the unbalanced reaction below into your lab notebook. Balance the reaction by adding coefficients. (1) KI (aq) Pb(NO,), (aq) KNO, (aq) Pbl, (s) 2. a) Which trial are you assigned? b) Copy the data table below into your notebook. Watch video A (make sure it's the correct trial!) and collect your data. You may need to pause or rewatch the video, it goes quickly. (1.5) Mass of Empty Beaker (g) Mass of Beaker+ solid Pb(NO,)。(g) Volume of 1.0 M KI (aq) (mL) For the following calculations, show all your work for full credit. 3. What mass of solid Pb(N0,), was added to the beaker? (1) 4. If the solid Pb(NO,), was dissolved in 45 mL of water, what is the molarity of the Pb(NO,)。 solution? (2.5) 5. Which compound is the limiting reactant? (4) 6. What mass of lead (II) iodide (PbL,) should be produced? (2) Part 2: 7. Watch video B (make sure it's the correct trial!) to see the complete reaction and collection of the product. Copy the data table below and record your data. (1) Mass of filter paper (g) Mass of filter paper + dried precipitate (g) 8. What mass of precipitate was collected? Show your work. (1) Calculate the percent yield for the reaction. Show your work. (2) 10. For your trial, which three ions were present in the filtered solution at the end of the reaction? In other words, which three ions are still dissolved at the end of the reaction? Defend/explain your 9. answer. (3) 11. Watch video C - watch both tests for your trial and record your observations. (1) a) Add lead (II) nitrate - b) Add potassium iodide - 12. These tests were conducted to prove the identity of the limiting reactant. Considering your answers to the previous two questions, describe how these tests support the prediction you made in question 5 about which compound is the limiting reactant. (2)

なぜ答えがbなのか詳しく教えていただきたいです🙇🏻‍♀️ (問題文と選択肢の意味はわかります。)

9. A mixture of 0.50 mol H。(6) and 0.50 mol N。(q) is introduced into a 15.0 liter container having a pinhdle leak at 30°C. After a period of time, which of the following is true? The partial pressure of H, exceeds that of N, in the container. b) The partial pressure of N, exceeds that of H, in the container. C. The partial pressures of the two gases remain equal. d. The partial pressures of both gases increase above their initial values.

なぜ答えがbなのか分かりやすく説明して頂きたいです🙇🏻‍♀️

9. Amixture of 0.50 mol H。(G) and 0.50 mol N,(g) is introduced into a 15.0 liter container having a pinhdle leak at 30℃. After a period of time, which of the following is true? a. The partial pressure of H, exceeds that of N, in the container. b) The partial pressure of N, exceeds that of H, in the container. C. The partial pressures of the two gases remain equal. d. The partial pressures of both gases increase above their initial values.

解き方が分かる方、お願いします。m(_ _)m

EEモキモキギキモEi hese atoms were formed in the firstfew secods afler the Big Bang th event that marked | LegHmpimeoftheuniverwe HHowewcr thereisgttle free hydrogenon Fartb becausc Hmolecule mgYem hh moeat ueh high merge speeds at mey exape fom the Erths rmeYitr Most of the Earthis hydrogen is preeent as water either im the oceans or trappcd imside minerily ) mdclays Hydrogenisalsofoundimthehydrocarbons*! that make up thefossilfuelscoaL[ ん md naturml gas ILiaksenergytorelesee om these compounds Ifwe yaptto we SS a fel we must produce the gas using lcss energy than it generates when bumed. Beceuse water sits only combuston*3 prodoct_ hydrogen bnrms without poluting the ai Cr onibuitng signifcantly to the grecnhouse cfect*3 Coal[ A ] and natural gaN ae becoming increasingiy rare.but there isenough waterin the oceans to gencrate the hydrogen fuel we shall cver need. Hydrogen is obtaincd from water by elecrolysis** but that prOceSt requires electricity that has been gencrated esewhere。 Chemists are currently Seeing as Of using sunlight to drive the water-spitting reaction.the "decomposieon*" of ater eiemen Waterspbtting reacton : 2HzO(ianid) 一 2Hz(eas) Oz(gssy At present most commercial hydrogen is obtagted ss a byproduct*fof[ A ]refmmgYPma Sequence of two catalyzed reactons*9。 The gst is a reiorming reacton*io in which a jjdrocarbon and esm sre cnnweried into cartbon monoxide*! and hydrogen ovcr a nickl catalystYP: 。keforning reaction : CH(gss) +HkO(gas) 一 CO(gay) +3H(gy) The miiture ofproducts caled synthess gas "js the staring point for manufacture of many dher ompounds inciuding 。methanol Tbe reforming reacton is folowed by the shif reaction*1 im which the carbon monoxide in the synthesis gas reacts with more Water Shi reacion : CO(gms) +HLO(gas) 一 CO:(m) +Hktgs) Hydrogen is lso prepared pn smal amoupts. ja he laboratory by reducing hydrogen ions from strong acid with a metal (て Ama aaaL Janeu Chenical Prmepke: The Qwex cr msght 001 W.了Feman をCo から一 更して引有8) 1、 hydrocarbon : 庶化水素 2.combuston : 朱 3. greenhouse cert:温宅効果 4 Jayai : 電気分狂 5.photochemica 光化学的な 6.decomposiion 分角 yproduct: 硬生成物 8. rehing:柄製 9.caiyzed reacton :衣区応 10 ngreacdon : 折反計 1. cmrbonmonoridei 一誠化素 12.cataibet i角 。 15. synhess gms :全成ガス 14. shift reacton : シフト反応