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化学 高校生

ここはなぜ1000じゃなくて100なんですか?

発展例題13 酸化還元滴定 0.252gのシュウ酸の結晶 (COOH)2・2H2O を水に溶かして, 問題189・190 正確に100mL の溶液を 調製し,その中から 25.0mLを正確にとり 希硫酸で酸性にした。これを温めながら 濃度不明の過マンガン酸カリウム水溶液を少量ずつ加えていくと, 20.0mL加えたと ころで,反応が完了した。 (COOH)2 →>> MnO4-+8H++5e ← Mn2++4H2O 2CO2+2H++2e- 316103 (1) 下線部①,②の操作で用いられる器具の名称を記せ。 (2) 下線部③で,反応がちょうど完了した点をどのように決めるか。 (3) この過マンガン酸カリウム水溶液の濃度は何mol/Lか。 ■ 考え方 (2) COOH)2 が残っている 間は, MnO4-がMn2+とな るため, ほぼ無色になる。 (3) 滴定の終点では,次の 関係が成り立つ。 酸化剤が受け取った電子の 物質量= 還元剤が放出した 電子の物質量 (3) (大直丸 1S) 下 解答 mol (1) ① メスフラスコ ② ホールピペット 外 (E) J 改) (2) 滴下した過マンガン酸カリウム水溶液の赤紫色が, 消え ずに残る点を終点とする。 (3) した 1mol の MnO4-は5molの電子を受け取り, 1molの (COOH)2は2mol の電子を放出する。 KMnO4 水溶液の濃度 を c[mol/L] とすると, (COOH)2・2H2O=126g/mol から, 旬を配 c[mol/L]× 20.0 20.252 -L×5= 1000 c=1.00×10-2mol/L mol x 126100 20 25.0 -×2 ( 改)

解決済み 回答数: 1
数学 高校生

181(2)です。 解説の下から3行目、「R(1-R)は最大値1/4をとる」からその下の「したがって、〜」の部分で質問です。 なぜ「R(1-R)は最大値1/4をとる」から最小のnを導くことができるのでしょうか。

E(X) +VO 181. (1) Mは二項分布 B(n, 1/2)に従うから、 1 n E(M)=n=2, V(M)=n.- 22 4 ここで, X=10M+5(n-M)=5M+5n であるから, E(X)=E(5M+5n)=5E(M)+5n=5・1/2+5, (1)X を M を用いて表し, E(aM+6)=aE(M) +6 V (aM+6)=d2V (M) ( a, b は定数) を利用する。 15 = 2" また,V(X)=V(5M+5n)=52V(M)=4 25 -n )+b 25 o(X)=1 n=- 4 5 del n 2 6(X) E(X) 1 <0.1 となるとき, 512 n=- <0.1 2 2 3√n 10 1º<√n, n> 3 X) 100 9 =11.111... したがって、条件を満たす最小の自然数nの値は, 12 (2) 信頼区間の幅は, R+1.96X, XR(1-R) =2x1.96× -R)) -(R-1 n R(1-R) R-1.96× n R(1-R) = 3.92× n n R(1-R) よって、信頼区間の幅が 0.1以下となるとき, (2)R は, 10円硬貨を取り出す標 本比率であるから, 0以上1 以下の値をとる。 この範囲で、Rの値によらず つねに信頼区間の幅が 0.1以 下となるような自然数nの最 小値を求める。 3.92X R(1-R) ≦0.1, n 39.2×√R(1-R) Sn 1536.64 × R (1-R)≦n R: ここで,R(1-R)=(R-1/2)+ -R-12122+1/2より、R=/1/23 のとき, R(1-R) は最大値 - をとる。 したがって n≧1536.64× 1=384.16 よって、条件を満たす最小の自然数nの値は, 385

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英語 高校生

下から15行目のthrow whichのthrow とはなんですか?

y II Day 12 15 5 Negro Leagues Baseball was a collection of major and minor-league baseball leagues that were the first to showcase black team sports on intertwined with the African American and American experience not only a national scale. Launched in 1895, the leagues, as with jazz, became as a cultural element, but as a lucrative business endeavor. team The leagues were not under central management, and schedules and composition League, were changeable from season to season. Appearance and disappearance of leagues was common: the National Colored Baseball for instance, collapsed after only two weeks of operations. Latins, especially Cubans, were also a significant presence on teams. In these ways, the Negro Leagues were quite similar to their white counterparts which would eventually consolidate into Major League Baseball. Blacks near the beginning of the 20th century had only a fraction of whites' purchasing power, so the emergence of the Negro Leagues might have seemed unlikely. However, the Negro Leagues had two main draws that accounted for its business success. The first was a deep reserve of athletic talent. After blacks were formally excluded from white leagues in the 1880s, the Negro Leagues were the sole organization through which black players could work professionally. The quality of Negro Leagues 20 players was high, and substantiated through exhibition matches between Negro Leagues and Major League teams: over the years, both had their fair share of wins and losses in these matches. Another reason for the success of the Negro Leagues was an increasingly affluent black fan base. Driven by American industrialization, blacks were concentrating in major cities such as New York City, Chicago, and Atlanta. Usually barred by custom-and in the South by law-from attending many white entertainment outlets, blacks turned to Negro Leagues games. As a result of these factors, by the 20th century the Negro Leagues were earning a combined millions of dollars. This profitability ended with the desegregation of Major League Baseball. Black fans began attending Major League games, starving the Negro Leagues of its core revenue source. By 1951, the Negro Leagues had ended, although a succession of black star athletes in the Major League had begun.

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