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化学 高校生

ニトロベンゼンからアニリン塩酸塩を生成する際のスズは還元剤として使われるのですが、この反応式見ると塩酸はスズを酸化してる時言っていいんですかね??

濃硫酸を少しずつ加えていくようにして混酸をつくる。 生成したニト ロベンゼン (密度1.2g/cm²) は水に不溶な淡黄色の油状物質で,混酸 (密度約1.6g/cm²) には浮くが、 水 (密度1.0g/cm²) に入れると沈む。 [実験2] の前半ではニトロベンゼンの還元をしている。 還元剤と酸化 剤のはたらきは, Sn + 4HCl → → SnCl + 4H+ + 4e C6H5NO2+6H++ 6e → C6HsNH2 + 2H2O ①式×3+②式×2 より, 2C6H5NO2 + 3Sn + 12HCl → 2C6H5NH2 + 3SnCl4 +4H2O *①4 塩酸が過剰の場合は,生成物はアニリン塩酸塩となる。 2C6H5NO2 + 3Sn + 14 HCl 2C6H5NH3C1 + 3SnCl4 + 4H2O 反応物のニトロベンゼンは水に不溶なので, 濃塩酸とは二層に分かれ ているが, 生成物のアニリン塩酸塩は水に溶けて均一な溶液となる。 実験2] の後半では弱塩基遊離反応によりアニリンに戻している。 NHBCI + NaOH → (弱塩基の塩) (強塩基) NH2 + NaCl + H2O (弱塩基) (強塩基の塩) リンをジエチルエーテルに溶かし, 抽出する。 その後,さらし粉 赤紫色に呈色することで, アニリンを検出する。 験3]ではアニリンをジアゾ化している。 NH2 -N+ + NaNO2 + 2HCI ← NEN] CI- CI + NaCl + 2H2O 塩化ベンゼンジアゾニウム 物の塩化ベンゼンジアゾニウムは不安定な化合物で, 5℃以上で 分解が起こり, フェノールと窒素が生成する。 N₂CI + H2O OH + N2 + HC1 ■]の反応はジアゾカップリングで, アゾ化合物 -NC1 +

解決済み 回答数: 1
英語 中学生

1.(1)②、(2)②、(3)①、(4)③④⑧⑩、(5)③④⑤、(6)③④、(7)①④⑥、(8)①②③⑥、(9)の解説をして欲しいです。3枚目が答えです

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未解決 回答数: 0