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25.
a. Brazil, in which population is about 214 million, is a huge country
which covers nearly half of South America.
b. Brazil, in which population is about 214 million, is a huge country that
it covers nearly half of South America.
c. Brazil, whose population is about 214 million, is a huge country which
covers nearly half of South America.
d. Brazil, whose population is about 214 million, is a huge country that it
covers nearly half of South America.

Answer 1

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大吉

おかしいと思われるところを線引いてみました。
in which は動詞の後にくるのをwhichの前に持ってくるのでbe+inはおかしい。
that はcountry(Brazil)にかかるので主語、その後にまたitとありおかしい。