操作2と操作3は逆でもいいのですか？

発展例題28 芳香族化合物の置換基の配向性 ものがある。 一般に,オルト位 o-やパラ位カーで置換反応をおこしやすい官能基をもつ物質には次の 問題308 CI NH2 OH (オルト・パラ配向性) アニリン クロロベンゼン フェノール 一方,メタ位m-で置換反応をおこしやすい官能基をもつ物質には次のものがある。 NO2 .SO3H COOH ( メタ配向性) ニトロベンゼン ベンゼンスルホン酸 安息香酸 このことを利用すれば, 目的の化合物を効率よくつくることができる。 この情報をもとに,除草剤の原料であるm-クロロアニリンを,次のようにベンゼンから 化合物 A, B を経て合成する実験を計画した。 CI 操作 1 操作2 操作3 化合物 A 化合物 B ・NH2 ベンゼン m-クロロアニリン (木) 操作1~3として最も適当なものを,次の①~⑥のうちからそれぞれ1つずつ選べ。 ① 濃硫酸を加えて加熱する。 ② 固体の水酸化ナトリウムと混合して加熱融解する。 ③鉄を触媒にして塩素を反応させる。 ④ 光をあてて塩素を反応させる。 ⑤ 濃硫酸と濃硝酸を加えて加熱する。 ⑥ スズと濃塩酸を加えて反応させたのち, 水酸化ナトリウム水溶液を加える。 考え方 アミノ基はニトロ基を還 元して生成するので,ニ トロ基とCIがメタ位 になる条件を考える。 ①~⑥の操作では次のよ うな変化がおこる。 ①スルホン化 ② アルカリ融解 |解答 DOE クロロベンゼンは③の塩素化で生じる。 アミノ基はニトロ基を還元 すればよいので, ⑤のニトロ化を行ったのち, ⑥の還元をすればよい。 -CIはオルト・パラ配向性なので, 塩素化をしたのちにニトロ化を 行うと, オルト位, パラ位にNO2が入ってしまう。そこで,まず ベンゼンをニトロ化してニトロベンゼンとし,次に塩素化を行うと, ニトロ基はメタ配向性なので, m-クロロニトロベンゼンが得られる。 これを還元すると, m-クロロアニリンとなる。 ③塩素化(置換) ④ 塩素化 (付加) ニトロ化 ⑥ 還元 ( 操作 1 操作 2 操作3 ニトロ化 NO2 塩素化 ~NO2 還元 -NH2 操作 1: ⑤ 操作 2: ③ 操作36

赤線の略、文法が分かりません。 数が多くてすみません💦

【3】 次の文章とグラフを読んで問いに答えなさい。 現実? ? ✓ ~したい? Today, the eating habits of Japanese people have changed. More people like to eat bread and pasta, They also enjoy a lot of different dishes from other countries more often. ? Japan import's a lot of "produce from foreign countries. 2177 Look at the graph. These five countries spend a lot of money to import produce from SR? other countries. Among them, Japan spends the most and spends about 30 “billion dollars more than the UK. Russia doesn't spend as much as Germany but spends about 2 billion 日本は30億 dollars more than Italy. アメリカより使ってる? Why does Japan import so much produce? There are many reasons for this. Let's think about two of the reasons. One reason is the change in the favorite foods of Japanese people. ①Dishes from foreign countries are ( a ) among Japanese people, but some things ( b ) to cook those dishes are not available in Japan. The "shortage of farmland is another reason. About 70% of land in Japan is not good as farmland, because the land is in the mountains and is (②) with tree. And on some parts of the land which is good as farmland, people have built houses, shops and so on. Can Japan always import a lot of produce? It is not ( 3 ) to this question. In some parts of the world. *natural disasters like floods and *livestock epidemics sometimes damage produce which Japan needs. 4 (1. thing 2. should 3. we 4. 5. remember 6. another 7. there). If world peace is broken, maybe it will be difficult for Japan to import things. 4 another. There is things we should vem *produce billion 101 shortage natural disasters livestock epidemics

並び順を教えてください🙏

John will be late for the first game, so we'll just (7 do have make I to with) ten players.

答え合ってますでしょうか🥹🥹 誤字訂正2番がわかりません、、

この大門1の解説がほしいです。

(1) 文法問題 1 適当な語(旬) を選びなさい。 (1) It is strange for Ken ( ) with us. 1. do not agree 2. does not agree 3. not to agree <梅花短大 > 4. not agree (2) It was careless ( ) you to leave your key in your car. <京都産大 > 1. in 2. of 3. to 4. with (3) The wind was not ( ) to prevent us from skydiving. 1. as strong 2. as strong as 3. so strong 4. so strong as <センター追試> (4) It is ( experience. 9) that an experienced person will do better than someone without 1. needless for saying 4. needless saying 2. needless to say 3. needless in saying <四天王寺国際仏教大 (5) All you have to do is (a) this letter.smo rique 2 to have to post 3 for posting 4. to be posted <大阪産

（5）おねがいします‼️‼️

12 数学 3 右の図のように,反比例のグラフy=1/4上に点A(29)があり,この反比例のグラフと x 放物線y=bx2 が点Bで交わっています。 点Bのx座標は3で, 直線AB と x軸, y軸との交点をそれぞれC, Dとします。 また,放物線y=bx2上に x 座標が負である点P (t, bt2)があります。 (1) αの値を求めなさい。 (2)の値を求めなさい。 (3)直線ABの式を求めなさい。 。 (4) AOACの面積と△ODP の面積が等しくなるような 点Pの座標を求めなさい。 (5)点Pのy座標が点Dのy座標よりも小さいとき, △OBD の面積と BDPの面積が等しくなるような 2 y= 点Pの座標を求めなさい。 (t,bt³). (229) C=30C BOOK B #64 BW В VCO VDOECD SIAS VBCD にこ ① B (3,6) C (50) x y= 18 y=3x+15

なぜ1が答えになるのですか？ 教えてください。

(1) ( 2 Must ) it be true that 70% of Americans believe in angels? 1 Can 3 Does 4 May

誤りを含む下線部がどれなのか教えていただきたいです。

The importance of documentaries is public as a social phenomenon. linked to a notion of the [a]. The philosopher John Dewey argued persuasively that the public-so crucial to the health of a democratic society is not just individuals added up. A public is a group of people [b]. who can act together for the public good and so can challenge the deep- [c]. seated power of business and government. It is an informal body that can [d] come together in a crisis if necessary. There are as many publics as there are occasions and issues to call them forth. We can all be members of any if we have a way to communicate each other about the particular public [e]. shared problems we face. Communication, therefore, is the soul of the public.

かっこに共通する単語を教えていただきたいです。わかる方お願いします🙏

I received a ( ) from my grandmother. She doesn't know how to send e-mails. You have to start an English sentence with a capital ( ).

数を聞く問題で、答え方がこれと、もうひとつあるらしいのですが、なにか教えて欲しいです🙇‍♀️③

40c (青森) 73 次の英文はケンタ (Kenta)のスピーチである。これを読んで、あとの質問に英語で答えなさい。 I get up at six thirty and have breakfast every morning. But a week ago, I got up at seven forty because I finished my homework and went to bed very late. I didn't have time to have breakfast and came to school without it I was hungry during class and became *sleepy in the morning. I usually play volleyball well in *PE but I couldn't play it well that day. I thought having breakfast was very important, so I asked my *classmates some questions about breakfast. There are forty students in our class. Thirty-six classmates had breakfast. Three of them had only milk for breakfast. Two of them had *snacks for breakfast. There four classmates who didn't have breakfast. They felt bad and tired. were When we have breakfast, we can study harder and play sports better at school. Let's have it every morning and enjoy our school lives. 〔注〕 sleepy : 眠い PE: # classmate(s): 1 What time does Kenta get up every morning? He gets up at six thirty. Diag 2 Why was Kenta hungry during class? snacks: Because he didn't have time to have breakfast to school without it. 3 How many students are there in Kenta's class? There are forty students in his class TO and Came